Mono-(6-ethanediamine-6-deoxy)-beta-Cyclodextrin
The primary amine in the ethylenediamine group is a good bond chain structure, which can be bonded with carboxylic acids, esters, anhydrides, aldehydes, ketones, halogens, etc., under mild conditions. Ethylenediamine cyclodextrin is a good supramolecular structure of the intermediate.
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Specifications | |
Name | Mono-(6-ethanediamine-6-deoxy)-beta-Cyclodextrin |
CAS No. | 60984-63-6 |
Synonyms | Mono-(6-ethanediamine-6-deoxy)-β-Cyclodextrin |
Molecular Formula | C44H76N2O34 |
Molecular Weight | 1177.07 |
Appearance | light yellow or white powder |
Solubility of Mono-(6-(diethylenetriamine)-6-deoxy)-beta-Cyclodextrin | ||||||
Solvent | Water | Ethanol | Acetone | Ether | Methanol | DMF |
Solubility | 0.5 ≤ X<5ml | 50ml≦X<500ml | X>5000ml | X>5000ml | X>5000ml | 15ml≦X<50ml |
Remark | X means solubility.
Temperature T=25 ℃, |
The ethylenediamine group in the structure of ethylenediamine still retains the complexation ability of ethylenediamine, and can be complexed with transition metals (Fe, Co, Ni, Pt, etc.) to build an artificial simulated enzyme system of cyclodextrin, which has a good catalytic effect for specific reactions.
At the same time, ethylenediamine complexation ability is equivalent to adding another variable to the cyclodextrin cavity recombination ability, and multiple recognition can be realized in supramolecular recognition system. For example, under different pH conditions, the protonation degree of the ethylenediamine group is different, the position of the ethylenediamine group is different relative to the cavity, and the force of the guest molecule is different.
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